Users can configure the startup session characteristics for every label at which they log in..
You must be logged in to a multilevel session.
Create workspaces at every label.
For details, see How to Add a Workspace at a Particular Label.
Configure each workspace as you want the workspace to appear.
Go to the workspace that you want to see when you log in.
Save this current workspace.
For details, see How to Perform Some Common Desktop Tasks in Trusted Extensions.