Unfortunately, the .rhosts file presents a major security problem. While the /etc/hosts.equiv file is under the system administrator's control and can be managed effectively, any user can create a .rhosts file granting access to whomever the user chooses without the system administrator's knowledge.
In a situation in which all of the users' home directories are on a single server and only certain people have superuser access on that server, a good way to prevent a user from using a .rhosts file is to create an empty file as superuser in their home directory. You would then change the permissions in this file to 000 so that it would be difficult to change it, even as superuser. This would effectively prevent a user from risking system security by using a .rhosts file irresponsibly. It would not, however, solve anything if the user is able to change the effective path to his or her home directory.
The only secure way to manage .rhosts files is to completely disallow them. See "How to Search for and Remove .rhosts Files" for detailed instructions. As system administrator, you can check the system often for violations of this policy. One possible exception to this policy is for the root account--you might need to have a .rhosts file to perform network backups and other remote services.